1) Shri E. M. S. Namboodiripad
(Apr 5, 1957-Jul 31, 1959) CPI
President’s Rule (Jul 31, 1959-Feb 22, 1960)
2) Shri Pattom Thanupillai
(Feb 22, 1960-Sep 26, 1962) Praja Socialist Party
3) Shri R. Sankar
(Sep 26, 1962-Sep 10, 1964) INC
President’s Rule(Sep 10, 1964-Mar 6, 1967)
4) Shri E. M. S. Namboodiripad
(Mar 6, 1967-Nov 1, 1969) CPM
5) Shri C. Achutha Menon
(Nov 1, 1969-Aug 1, 1970) CPI
President’s Rule (Aug 1, 1970-Oct 4, 1970)
6) Shri C. Achutha Menon
(Oct 4, 1970-Mar 25, 1977) CPI
7) Shri K. Karunakaran
(Mar 25, 1977-Apr 25, 1977) INC
8) Shri A.K. Antony
(Apr 27, 1977-Oct 27, 1978) INC
9) Shri P. K. Vasudevan Nair
(Oct 29, 1978-Oct 7, 1979) CPI
10) Shri C. H. Mohammed Koya
(Oct 12, 1979-Dec 1, 1979) MUL
President’s Rule (Dec 1, 1979-Jan 25, 1980)
11) Shri E. K. Nayanar
(Jan 25, 1980-Oct 20, 1981) CPM
12) Shri K. Karunakaran
(Dec 28, 1981-Mar 17, 1982) INC
13) Shri K. Karunakaran
(May 24, 1982-Mar 25, 1987) INC
14) Shri E. K. Nayanar
(Mar 26, 1987-Jun 17, 1991) CPM
15) Shri K. Karunakaran
(Jun 24, 1991-Mar 16, 1995) INC
16) Shri A. K. Antony Mar
(22, 1995 May-9, 1996) INC
17) Shri E. K. Nayanar
(May 20, 1996-May 13, 2001) CPM
18) Shri A. K. Antony
(May 17, 2001-Aug 29, 2004) INC
19) Shri Oommen Chandy
(Aug 31, 2004-May 18, 2006) INC
20) Shri V.S. Achuthanandan
(May 18, 2006-May 14, 2011) CPM
21) Shri Oommen Chandy
(May 18, 2011-May 24, 2016) INC
22) Pinarayi Vijayan
(May 25, 2016-May 19, 2021) CPM
23) Pinarayi Vijayan
(May 20, 2021-Present) CPM